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Molecular orbitals in Mo6Cl84+and W6Cl8/4+clusters

✍ Scribed by D. V. Korol'kov; V. N. Pak


Publisher
SP MAIK Nauka/Interperiodica
Year
1974
Tongue
English
Weight
472 KB
Volume
14
Category
Article
ISSN
0022-4766

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πŸ“œ SIMILAR VOLUMES


Low energy electronic levels in the [Mo6
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Low temperature magnetic susceptibility and magnetic circular dichroism spectra are used to demonstrate that. in contradiction to the currently held hypothesis, the ground state of the [MohCls14+ion does not arise from a closed-shell configuration.

Compounds with Cluster Cations together
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Compounds consisting of both cluster cations and cluster anions of the composition [(M 6 X 12 )(EtOH) 6 ][(Mo 6 Cl 8 )Cl 4 X 2 ] Β΄n EtOH Β΄m Et 2 O (M = Nb, Ta; X = Cl, Br) have been prepared by the reaction of (M 6 X 12 )X 2 Β΄6 EtOH with (Mo 6 Cl 8 )Cl 4 . IR data are given for three compounds. The