Molecular orbitals in Mo6Cl84+and W6Cl8/4+clusters
β Scribed by D. V. Korol'kov; V. N. Pak
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1974
- Tongue
- English
- Weight
- 472 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0022-4766
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Low temperature magnetic susceptibility and magnetic circular dichroism spectra are used to demonstrate that. in contradiction to the currently held hypothesis, the ground state of the [MohCls14+ion does not arise from a closed-shell configuration.
Compounds consisting of both cluster cations and cluster anions of the composition [(M 6 X 12 )(EtOH) 6 ][(Mo 6 Cl 8 )Cl 4 X 2 ] Β΄n EtOH Β΄m Et 2 O (M = Nb, Ta; X = Cl, Br) have been prepared by the reaction of (M 6 X 12 )X 2 Β΄6 EtOH with (Mo 6 Cl 8 )Cl 4 . IR data are given for three compounds. The