Molecular orbital theory of electron donor-acceptor complexes
โ Scribed by R. L. Flurry
- Publisher
- Springer
- Year
- 1971
- Tongue
- English
- Weight
- 668 KB
- Volume
- 23
- Category
- Article
- ISSN
- 1432-2234
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๐ SIMILAR VOLUMES
WC present a simple theoretical model which qualitatively explains the previously reported unusual features of the fesonance Raman (RR) excitation profies of electron doaorlacceptor complexes of TCNJZ with aromatic donors, in particuiar the pronounced red-shift of the RR cxcitation protรฏle vis 5 vis
## Abstract The wave functions of donorโacceptor pairs before and after electron transfer are written as a product of the electronโvibrational wave functions of the donor and acceptor with allowance for the change in the number of electrons on these particles by one after transition. In this approx
The influence of solvent polarity on spectroscopic and thermodynamic properties of molecular electron-donor-acceptor (EDA) complexes is discussed. Analysis of experimental data leads to the conclusion that the ground state of EDA complex is destabilized with increasing polarity of solvent and this i