Molecular Orbital Model for Ion Polar-Molecule Capture Collisions
β Scribed by Xu, Ming; Dillon, Stephanie; Kimel, J. Daniel; Dougherty, Ralph C.
- Book ID
- 127095788
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 205 KB
- Volume
- 104
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
Hiadt&d rotation of polar molecules in capture collisions with ions has been studied by numerical trajectory catculations. Compute+-made movies furnish a convenient visual means for observing the relative motion of the ion-molecule pair, as we11 as hindering of the di,noie by the incident ion. The d
## Abstract | I. | Introduction | 142 | | II. | Reaction Efficiency | 144 | | III. | Ion PolarβMolecule Collisions | 145 | | IV. | MomentumβTransfer IonβMolecule Collisions | 146 | | V. | Summary | 151 | | Acknowledgments | 151 | | References | 151 | This paper reviews some applications of quantum
The average dipole orientation (AEO) theory of ion-polar molecule apiure collisions is reformuhta3 in terms of the average cosine, cos0. The earlier formulation USA an average angle, S, in the effective potential that is used to develop cxpressions for the cross section and rzte constant. The cos 0