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Molecular Modulation Mass Spectrometry Kinetic Study of the ClO Free Radical

✍ Scribed by Ching-Hsong Wu; Harold Johnston

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
837 KB
Volume
81
Category
Article
ISSN
0037-9646

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πŸ“œ SIMILAR VOLUMES

Kinetic studies of free radical reaction
Kinetic studies of free radical reactions by mass spectrometry. I. The reactions SO + NO2 and ClO + NO
✍ Michael A. A. Clyne; Alexander J. Macrobert πŸ“‚ Article πŸ“… 1980 πŸ› John Wiley and Sons 🌐 English βš– 897 KB

## Abstract A novel technique is described for forming ground‐state SO __X__^3^Ξ£^ο£Ώ^ radicals free of reactive impurities in a discharge‐flow system. Mass spectrometric detection of SO and ClO free radicals has been used to study the kinetics of the following reactions at 295 K: equation image

Kinetic studies of free radical reaction
Kinetic studies of free radical reactions by mass spectrometry. II. The reactions of SO + ClO, SO + OClO and SO + BrO
✍ Michael A. A. Clyne; Alexander J. Macrobert πŸ“‚ Article πŸ“… 1981 πŸ› John Wiley and Sons 🌐 English βš– 604 KB

## Abstract The rates of several novel elementary reactions involving ClO, BrO and SO free radicals in their ground states were studied in a discharge‐flow system at 295 K, using mass spectrometry. The rate constant __k__~2~ was determined from the decay of SO radicals in the presence of excess ClO