The ti = 0, I-doubler transitions in the fat excited state of the bending vibration of 16012~3% have been investigated using the molecular-beam electric-resonance method. The I-doubling constant up to second order in JU+lI has beea derived. The electric and magnetic properties obtained are the elect
Molecular constants of OCS isotopes in the (0110) vibrational state measured by molecular-beam electric-resonance spectroscopy
β Scribed by J.M.L.J. Reinartz; A. Dymanus
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 454 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
TheaJ= OJ-doublet txnsitionsofOCS isotopes('6012C32S, I6 I2 33 I6 '* 34 0 C S, 0 C S, '6013C32S and "O'*C3*S) in the (01' 0) vibrational state have been measured in a molecular-beam electric-resonance spectrometer equipped with a nozzle source. Rotation-vibration coupling constams and electric dipole moments have been determined for all iso topes, and the spin-rotation and the quadrupole coupling constants for the %S nucleus in '60'2C"S in the vz=O and vz=l states.
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The molecular-heam electric-resonance method has been used to measure the radio frequency spectra of CsF in the rotational state J= I and vibrational states I\* = 0. 1. . . . . 8. The anal\-sis of the spectra yields rhe electric dipole moment and the quadrupole coupling constant as functions of I'.