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Molecular complexes of p-benzoquinonechlorimides with aromatic π-donors

✍ Scribed by P. Venuvanalingam; U.Chandra Singh; N.R. Subbaratnam

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
452 KB
Volume
37
Category
Article
ISSN
1386-1425

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✦ Synopsis

The charge transfer spectra of molecular complexes of chloro substituted p-benzoquinone(4)-chlorimides with aromatic lrdonors in cyclohexane have been studied. The interaction of 2,6dichloro p-benzoquinone with the same set of donors has also been studied. The spectroscopic and thermodynamic data indicate that the complexes are very weak in nature. A comparison of the absorption intensities and formation constants for these complexes shows that the contribution of charge transfer forces are not the only dominant stabilising factors.

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