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Molecular beam studies of 3-C3H5Br and 1-C3H5Br. Competition between photodissociation and isomerization

✍ Scribed by Wu-sheng Zhu; Xin-sheng Zhao; De-gang Han; Run-jun Li; Qing-hua Zhong; Qi-he Zhu

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
418 KB
Volume
204
Category
Article
ISSN
0009-2614

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✦ Synopsis

The photodissociation of 3-C,H5Br and 1-C,H5Br at 193 nm was studied by TUF technique in a pulsed molecular beam apparatus. The center-of-mass translational energy distribution P(E,) was obtained by simulation fitting the experimental TOF speo tra. Evidence was found for competition of hydrogen migration leading to isomerization, with dissociation of 1-CsH5Br. Rich intramolecular dynamics indicated by the experimental observation were discussed.

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