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Electron disappearance in pulse irradiated CH3Cl, C2H5Cl, CH3Br, and C2H5Br

✍ Scribed by Krishnan M. Bansal; Richard W. Fessenden

Publisher: Elsevier Science
Year: 1972
Tongue: English
Weight: 397 KB
Volume: 15
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(72)87005-2

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✦ Synopsis

Thermal electron attachment rafe ce~sf~rss have bsn determined fw CH$i, Cz H&I, CFfsBr, and C2 Hs Br using a microwave conductivity-puke radiolysis technique. Particukr exe was ta!+xn in purification of the compounds. \Kth CH3Cl and C2&Cl only upper limits of < 1.9 X lo-t5 3nd < 1.6 X 10-'5 cm3 molecule-* set-l, rcspectiWy, could be obtained. The values for CHsBr arid CzHsBr axe 7.3 X 1O-'2 and 2.8 X lo-I3 cm3 mofecult? SC-~, rcspectkly. NO evidence was found ia any of the four czes for three-body ebr?ron attachment in the presence of an escea of propane.

Volume 15, number 1

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