Molecular basis of catalytic reactions involving η3-allyl complexes of group 10 metals as key intermediates

Synthesis and Reactivity of [Ru(Cp*)(L)(

Synthesis and Reactivity of [Ru(Cp*)(L)(MeCN)2][PF6] (L = Ph2POMe or Ph2P-o-tolyl) and {Ru(Cp*)[Ph2PCH2C(tBu)=O](MeCN)}[PF6] Complexes, Their Involvement as Catalyst Precursors for Regioselective Allylic Substitution Reactions and Related [Ru(Cp*)Cl(Ph2POMe)(RCHCHCH2)][PF6] η3-Allyl Ruthenium(IV) Intermediates

✍ Bernard Demerseman; Jean-Luc Renaud; Loïc Toupet; Claudie Hubert; Christian Brun 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 219 KB 👁 1 views