✦ LIBER ✦

Synthesis and Reactivity of [Ru(Cp)(L)(MeCN)2][PF6] (L = Ph2POMe or Ph2P-o-tolyl) and {Ru(Cp)[Ph2PCH2C(tBu)=O](MeCN)}[PF6] Complexes, Their Involvement as Catalyst Precursors for Regioselective Allylic Substitution Reactions and Related [Ru(Cp*)Cl(Ph2POMe)(RCHCHCH2)][PF6] η3-Allyl Ruthenium(IV) Intermediates

✍ Scribed by Bernard Demerseman; Jean-Luc Renaud; Loïc Toupet; Claudie Hubert; Christian Bruneau

Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 219 KB
Volume: 2006
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.200501051

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Enolate-Phosphane Ligands Providing a To

Enolate-Phosphane Ligands Providing a Tool for the Selective Substitution of Triphenylphosphane by Carbon Monoxide or Trimethylphosphane in Complex {Ru(Cp)[η2-P,O-Ph2PCH2C(tBu)=O](PPh3)}[PF6], and Subsequent Reactivity Towards Terminal Alkynes

✍ Bernard Demerseman; Loïc Toupet 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 203 KB 👁 2 views

## Abstract The deprotonation under basic conditions of the keto‐phosphane ligand in complexes {Ru(Cp)[η^1^‐__P__‐Ph~2~PCH~2~C(=O)__t__Bu](PPh~3~)(L)}[PF~6~] (L = CO or PMe~3~) that arise from the addition of L to {Ru(Cp)[η^2^‐__P__,__O__‐Ph~2~PCH~2~C(__t__Bu)=O](PPh~3~)}[PF~6~] generates {Ru^+^(Cp