Molecular and crystal structures of bis{1,4-bis(1,2,4-triazol-1-yl)butane}dichlorocobalt(II)
✍ Scribed by L. Shen
- Book ID
- 111458390
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2009
- Tongue
- English
- Weight
- 277 KB
- Volume
- 35
- Category
- Article
- ISSN
- 1070-3284
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catena-Poly [[bis(thiocyanato-N) supplementary materials sup-4
The title compound, C 18 H 18 N 4 , lies on an inversion center. The benzimidazolyl moiety is essentially planar. Intermolecular NÐHÁ Á ÁN hydrogen bonds give rise to an in®nite helical chain structure, with the chains stacked by CÐHÁ Á Á% and %Á Á Á% interactions.
The coordination geometry of the Co II atom in the title complex, [Co(NCO) 2 (C 12 H 12 N 6 ) 2 ] n or [Co(NCO) 2 (bbtz) 2 ] n , where bbtz is 1,4-bis(1,2,4-triazol-1-methyl)benzene, is distorted octahedral, in which the Co II atom lies on an inversion centre and is coordinated by four N atoms from