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Molecular and crystal structure of (4-methylphenyl)-3-[2-(N-phenylamino)-6-(4-methylphenyl)] pyridylketone n-triphenylphosphosniumimine perchlorate

✍ Scribed by A. N. Chernega


Book ID
110632777
Publisher
SP MAIK Nauka/Interperiodica
Year
1999
Tongue
English
Weight
198 KB
Volume
40
Category
Article
ISSN
0022-4766

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Bis[4′-(4-methylphenyl)-2,2′:6′,2′′-terp
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In the title complex, [Mn(C 22 H 17 N 3 ) 2 ](ClO 4 ) 2 , the MnN 6 coordination geometry is distorted octahedral, involving the six N atoms of two 4 0 -(4-methylphenyl)-2,2 0 :6 0 ,2 00 -terpyridine (ttp) ligands. The two chelated ttp planes are almost perpendicular, with a dihedral angle of 89.1 (

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The title compound, C 34 H 32 N 2 , is formed as a result of the Diels-Alder reaction of N-benzylideneaniline and cyclohexen-2-one, catalyzed by zirconium tetrachloride. The molecule exists as the Z isomer. All three rings in the azabicyclo[2.2.2]octane system adopt boat conformations. The crystal p