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Modified method for calculation of centrifugal distortion constants for polyatomic molecules

✍ Scribed by S.J. Cyvin; G. Hagen

Publisher
Elsevier Science
Year
1968
Tongue
English
Weight
153 KB
Volume
1
Category
Article
ISSN
0009-2614

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✦ Synopsis

The method of Kivelson and Wikon for calculating centrifugal distortion constants (to,p 6) has been sim-& -. plified. The quantities may be obtained wirith the aid of certain elements referred to as Tap s rnstead of

πŸ“œ SIMILAR VOLUMES

An approximation method for evaluating c
An approximation method for evaluating centrifugal distortion constants in XH2 bent symmetric molecules
✍ T.R. Ananthakrishnan; C.P. Girijavallabhan πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 165 KB

It is shown'that the condition rwxx being a minimum with respect to Flz corresponds to setting Lzl = 0 in XY2 bern symmetric molecules. Expressions for the r,&6 elements under this condition invo!ve only the molecular geometry, atomic ma.sses and fundamental vii?rational frequencies. The -raag eleme