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Modification of the Wittig reaction to permit the stereospecific synthesis of certain trisubstituted olefins. Stereospecific synthesis of .alpha.-santalol

โœ Scribed by Corey, Elias J.; Yamamoto, Hisashi.

Book ID
120333697
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
394 KB
Volume
92
Category
Article
ISSN
0002-7863

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โœ Houpis, Ioannis N.; Shilds, Didier; Nettekoven, Ulrike; Schnyder, Anita; Bappert ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 578 KB

A stereospecific synthesis of the drug-candidate 1 is described. The synthetic sequence, aimed at accomplishing modularity and cost savings, features a series of organometallic steps to afford stereospecifically the desired trisubstituded olefin active pharmaceutical ingredient. Key developments con