Modern Arene Chemistry || Charge-Transfer Effects on Arene Structure and Reactivity
β Scribed by Astruc, Didier
- Publisher
- Wiley-VCH Verlag GmbH & Co. KGaA
- Year
- 2002
- Weight
- 889 KB
- Category
- Article
- ISBN-13
- 9783527601769
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π SIMILAR VOLUMES
The quenching of n,p\* singlet-excited 2,3-diazabicyclo[2.2.2]oct-2-ene, a very weak electron acceptor, by 26 aliphatic and aromatic amines was investigated in benzene. This photoreaction entails fluorescence quenching through exciplex formation with subsequent hydrogen atom abstraction from the N-H
## Abstract Thermodynamic and spectroscopic properties of the chargeβtransfer complex acenaphteneβtetrachlorophtalic anhydride were studied in different solvents. The corresponding thermodynamic and spectroscopic parameters were corrected for solvent competition. Only in this case were correlations