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Models for catechol 1,2-dioxygenase: Synthesis, spectroscopy and reactivity studies.

✍ Scribed by Viswanathan Rathinam; Mallayan Palaniandavar


Book ID
103568721
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
46 KB
Volume
43
Category
Article
ISSN
0162-0134

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## Abstract A series of mononuclear iron(III) complexes as models for intradiol cleaving catechol dioxygenases has been synthesized. In all six compounds, the iron(III) core is coordinated by the ligand [(6‐bromo‐2‐pyridyl)methyl]bis[(2‐pyridyl)methyl]amine (brtpa) which mimics the endogenous ligan