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Functional models for catechol 1,2-dioxygenase. Structure, reactivity, and mechanism

✍ Scribed by Que, Lawrence; Kolanczyk, Richard C.; White, Lloyd S.


Book ID
118008620
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
1016 KB
Volume
109
Category
Article
ISSN
0002-7863

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## Abstract A series of mononuclear iron(III) complexes as models for intradiol cleaving catechol dioxygenases has been synthesized. In all six compounds, the iron(III) core is coordinated by the ligand [(6‐bromo‐2‐pyridyl)methyl]bis[(2‐pyridyl)methyl]amine (brtpa) which mimics the endogenous ligan