Modelling and simulation of heterogeneous oxidation of methane on a platinum foil
β Scribed by O. Deutschmann; F. Behrendt; J. Warnatz
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 633 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0920-5861
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β¦ Synopsis
The heterogeneous oxidation of methane-air mixtures in a stagnation point flow onto a platinum foil is investigated numerically and results are compared with experiments. The analysis includes a detailed reaction mechanism in the gas phase as well as on the surface. The heterogeneous ignition occurring around 6OO"C, extinction, and autothermal behaviour are interpreted in terms of elementary steps at the gas-surface interface.
π SIMILAR VOLUMES
Using XPS linearly adsorbed CO species were observed on Pt foil, as a result of the surface reaction between H2 and CO2 at room temperature. A small amount of bridged CO species was also detected upon adsorption of pure CO2 over R foil, which suggests partial decomposition of CO\*. However, subseque