The interaction of small molecules (H,O, Or and CO\*) with polyphenylacetylene (PPA) thin films has been studied. The airexposed PPA interacts with the atmosphere water vapour, leading to covalently bonded OH groups on the basis of X-ray photoelectron spectroscopy (XPS) core-level spectra of C Is an
β¦ LIBER β¦
XPS observation of surface interaction between H2 and CO2 on platinum foil
β Scribed by M. Huang; A. Adnot; S. Suppiah; S. Kaliaguine
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 579 KB
- Volume
- 104
- Category
- Article
- ISSN
- 1381-1169
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β¦ Synopsis
Using XPS linearly adsorbed CO species were observed on Pt foil, as a result of the surface reaction between H2 and CO2 at room temperature. A small amount of bridged CO species was also detected upon adsorption of pure CO2 over R foil, which suggests partial decomposition of CO*. However, subsequent exposure to hydrogen removed the bridged CO species, while a small portion of additional linear CO species was formed.
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