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Modeling the Reaction Mechanisms of the Imide Formation in an N -( o -Carboxybenzoyl)- l -amino Acid

✍ Scribed by Wu, Zhijian; Ban, Fuqiang; Boyd, Russell J.


Book ID
121880159
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
211 KB
Volume
125
Category
Article
ISSN
0002-7863

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The reaction of o-amino aryl carboxylic
✍ Puwen Zhang; Eugene A Terefenko; Joseph Slavin πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 54 KB

The addition of Grignard reagents to the o-amino aryl carboxylic acids without any additive forms the tertiary carbinol as a major product. Unexpectedly, the aryl ketones are formed as the only isolated product if o-amino moiety of anthranilic acids is protected with Boc, trifluoroacetyl, and pivalo