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Modeling the Organic Nitrate Yields in the Reaction of Alkyl Peroxy Radicals with Nitric Oxide. 2. Reaction Simulations

✍ Scribed by Barker, John R.; Lohr, Lawrence L.; Shroll, Robert M.; Reading, Susan

Book ID: 126041078
Publisher: American Chemical Society
Year: 2003
Tongue: English
Weight: 160 KB
Volume: 107
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp034638j

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## Abstract Relative rate constants for the gas‐phase reactions of OH radicals with a series of alkyl nitrates have been determined at 299 ± 2 K, using methyl nitrite photolysis in air as a source of OH radicals. Using a rate constant for the reaction of OH radicals with cyclohexane of 7.57 × 10^−1