𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Modeling of the Free-Radical Copolymerization Kinetics with Cross Linking of Vinyl/Divinyl Monomers in Supercritical Carbon Dioxide

✍ Scribed by Quintero-Ortega, Iraís A.; Vivaldo-Lima, Eduardo; Luna-Bárcenas, Gabriel; Alvarado, Juan F. J.; Louvier-Hernández, José F.; Sanchez, Isaac C.

Book ID
118257333
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
679 KB
Volume
44
Category
Article
ISSN
0888-5885

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Modelling of crosslinking and cyclizatio
Modelling of crosslinking and cyclization in free-radical copolymerization of vinyl/divinyl monomers
✍ Zhu, S. ;Hamielec, A. E. ;Pelton, R. H. 📂 Article 📅 1993 🏛 Wiley (John Wiley & Sons) ⚖ 919 KB

## Abstract The Tobita‐Hamielec kinetic model of the crosslink density distribution is further elaborated and extended to incorporate divinyl loop formation. Divinyl loop formation, primary and secondary cyclization, and their effects on the elastically effective crosslink density distribution are

The combined statistical and kinetic mod
The combined statistical and kinetic modeling of gel/sol partition in free-radical copolymerization of vinyl/divinyl monomers
✍ Yingwu Luo; Zhixue Weng; Zhiming Huang; Zuren Pan 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 529 KB

Republic of China ## SYNOPSIS A general model of the gel/sol partition in the free-radical copolymerization of vinyl/divinyl monomers was developed, combining the statistical and kinetic modeling. It is emphasized that properties of the primary chains born at some conversion are effected by their

Modeling of effective crosslinking densi
Modeling of effective crosslinking density of the gel in free-radical copolymerization of vinyl/divinyl monomers
✍ Yingwu Luo; Zhixue Weng; Zhiming Huang; Zuren Pan 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 213 KB 👁 2 views

The concept of effective crosslinking density proposed by Scanlan is extended to heterogeneously crosslinking polymer. A kinetic-statistical model of effective crosslinking density of the gel is developed in free-radical heterogeneously crosslinking polymerization. The model is applied to the vinyl