✦ LIBER ✦

The combined statistical and kinetic modeling of gel/sol partition in free-radical copolymerization of vinyl/divinyl monomers

✍ Scribed by Yingwu Luo; Zhixue Weng; Zhiming Huang; Zuren Pan

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 529 KB
Volume: 34
Category: Article
ISSN: 0887-6266
DOI: 10.1002/(sici)1099-0488(19960115)34:1<65::aid-polb4>3.0.co;2-v

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✦ Synopsis

Republic of China

SYNOPSIS

A general model of the gel/sol partition in the free-radical copolymerization of vinyl/divinyl monomers was developed, combining the statistical and kinetic modeling. It is emphasized that properties of the primary chains born at some conversion are effected by their partner primary chains. It was concluded that the present model had overcome some shortcomings in Flory's and Tobita's model and facilitated taking the influence of kinetics into account, and was shown to be rather general for the free-radical copolymerization of vinyl/divinyl monomers.

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