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Modeling of Methyl Group Rotations in PMMA

โœ Scribed by Nicholson, T. M.; Davies, G. R.


Book ID
120921749
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
219 KB
Volume
30
Category
Article
ISSN
0024-9297

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Methyl tunnel frequencies, measured at 4 K, are found to be 455 +/- 8 kHz in methyl malonamide and 496 +/- 8 kHz in methyl ethyl ketone. The first is unaffected by deuteration of the amide groups. Measurements of the temperature dependence of the spin lattice relaxation time are also reported for me