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Modeling Dinuclear Copper Sites of Biological Relevance: Synthesis, Molecular Structure, Magnetic Properties, and 1H NMR Spectroscopy of a Nonsymmetric Dinuclear Copper(II) Complex. Microcalorimetric Determination of Stepwise Complexation of Copper(II) by a Nonsymmetric Dinucleating Ligand

✍ Scribed by Lubben, Marcel; Hage, Ronald; Meetsma, Auke; Feringa, Ben L.


Book ID
121337002
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
834 KB
Volume
34
Category
Article
ISSN
0020-1669

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First Complexes of a 4-Alkyl-3,5-di(2-py
✍ Marco H. Klingele; Peter D. W. Boyd; Boujemaa Moubaraki; Keith S. Murray; Sally 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 182 KB 👁 1 views

## Abstract The reaction of the new, bis(bidentate), potentially dinucleating ligand 4‐isobutyl‐3,5‐di(2‐pyridyl)‐4__H__‐1,2,4‐triazole (ibdpt) with M(ClO~4~)~2~·6H~2~O (M = Co^II^, Ni^II^ or Cu^II^) in a1:1 molar ratio in MeCN affords the dinuclear complexes [Co^II^~2~(ibdpt)~2~(MeCN)~2~(H~2~O)~2~