This review deals with copper and potassium complexes derived from flavonol and 1H-2-phenyl-3-hydroxy-4-oxoquinoline and covers various aspects, synthesis, spectroscopic features and chemical reactivity of these compounds. Application of these complexes as structural and their oxygenation reactions
Model systems for the CO-releasing flavonol 2,4-dioxygenase enzyme
✍ Scribed by József Sándor Pap; József Kaizer; Gábor Speier
- Book ID
- 104011066
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 915 KB
- Volume
- 254
- Category
- Article
- ISSN
- 0010-8545
No coin nor oath required. For personal study only.
✦ Synopsis
In this review structural and reactivity studies on the co-ligand containing model complexes for the flavonol 2,4-dioxygenase (FDO) are covered. The main focus is on the relationship between the structural features of the copper-containing model complexes, and their activity in the enzyme-like reactions. Some radical initiated reactions and catalytic systems will also be discussed.
📜 SIMILAR VOLUMES
In the Co(Salen)-catalyzed oxygenolysis of 3-methylindole giving rise to o-formyl-\_ aminoacetophenone, the actual active catalyst species has been found to be the Co(III)-(Salen) complex of an anion of the product. The catalysis involves activation of the substrate but not molecular oxygen. The act