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Model studies of iron-tyrosinate proteins

✍ Scribed by Pyrz, Joseph W.; Roe, A. Lawrence; Stern, Lawrence J.; Que, Lawrence


Book ID
115488196
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
886 KB
Volume
107
Category
Article
ISSN
0002-7863

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## Abstract It was found that the highly covalent nature of the metal‐ligand interactions in the Fe‐S cluster clearly played an important role in determining the reactivity of the sites. A semi‐empirical model, based on the Phillips theory of bonding was developed for quantitative explanation of co