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Model Electrochemical-Mass Spectrometric Studies of the Cytochrome P450-Catalyzed Oxidations of Cyclic Tertiary Allylamines

✍ Scribed by Jurva, Ulrik; Bissel, Philippe; Isin, Emre M.; Igarashi, Kazuo; Kuttab, Simon; Castagnoli, Neal


Book ID
126849939
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
233 KB
Volume
127
Category
Article
ISSN
0002-7863

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## Abstract Kinetic and mechanistic studies on the formation of an oxoiron(IV) porphyrin cation radical bearing a thiolate group as proximal ligand are reported. The **SR** complex, a functional enzyme mimic of P450, was oxidized in peroxo‐shunt reactions under different experimental conditions wit