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Regio- and stereochemical studies on the .alpha.-carbon oxidation of (S)-nicotine by cytochrome P-450 model systems

✍ Scribed by Peterson, Lisa A.; Castagnoli, Neal

Book ID: 126831121
Publisher: American Chemical Society
Year: 1988
Tongue: English
Weight: 584 KB
Volume: 31
Category: Article
ISSN: 0022-2623
DOI: 10.1021/jm00398a024

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## Abstract Kinetic and mechanistic studies on the formation of an oxoiron(IV) porphyrin cation radical bearing a thiolate group as proximal ligand are reported. The **SR** complex, a functional enzyme mimic of P450, was oxidized in peroxo‐shunt reactions under different experimental conditions wit