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Model-based measurement of diffusion using Raman spectroscopy

✍ Scribed by André Bardow; Wolfgang Marquardt; Volker Göke; Hans-Jürgen Koss; Klaus Lucas

Publisher
American Institute of Chemical Engineers
Year
2003
Tongue
English
Weight
429 KB
Volume
49
Category
Article
ISSN
0001-1541

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✦ Synopsis

Abstract

The measurement of diffusion coefficients in multicomponent liquid mixtures is still an open question. A new technique aimed at overcoming this deficiency is presented. It is based on Raman spectroscopy, which has been extended to obtain liquid concentration data of all components in a mixture simultaneously with high temporal and spatial resolution. The following data analysis uses model‐based methods. This provides a very flexible framework, allowing substantial reduction of experimental effort and time and the direct estimation of the diffusion coefficient as a function of concentration. Furthermore, the experimental procedure is improved using optimal experimental design techniques. This new methodology is validated for binary mixtures.

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