MOCVD of superconducting YBa2Cu3OT\_ 8 thin films using the novel fluorinated barium 13-diketonate complex [Ba(TDFND) 2 -tetraglyme] 1 in combination with [Y(TMHD) 3] 2 and [Cu(TMHD) 2] is reported. The Ba complex has a low melting point (72°C), is thermally stable to 200°C and allows reproducible a
✦ LIBER ✦
MOCVD of YBa2Cu3O7−x thin films using a Ba fluorocarbon-based precursor
✍ Scribed by K. Fröhlich; J. Šouc; S. Chromik; D. Machajdik; V. Kliment
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 414 KB
- Volume
- 202
- Category
- Article
- ISSN
- 0921-4534
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✦ Synopsis
We have prepared superconducting YBa2CU3OT_x films by MOCVD using fluorocarbon based Ba (hfa)2 precursor. The films were deposited at 500°C and annealed in low pressure (pO2= 10 -2 Pa) dry oxygen atmosphere as well as in argon/oxygen mixture in the presence of water vapour. The samples on a MgO single crystal substrate had Tc (R = 0) = 79 K and Jc = 10 + A/cm 2 at T= 30 K in zero magnetic field while the film on SrTiO3, annealed under the same conditions had Tc ( R = 0 ) = 86 K and Jc reached a value of l0 s A/cm 2 at T= 78 K.
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