[MnII(t-Bu)4salen]2 and Its Reaction with TCNE
β Scribed by Nate Petersen; James W. Raebiger; Joel S. Miller
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 246 KB
- Volume
- 159
- Category
- Article
- ISSN
- 0022-4596
No coin nor oath required. For personal study only.
β¦ Synopsis
II (t-Bu)
4 salen has been prepared and magnetically characterized as a dimer with weak intradimer coupling of J β«Ψβ¬ Ψ7.8 cm Ψ1 (J/k B β«Ψβ¬ 11 K) for H β«Ψβ¬ Ψ2JS a ' S b . The electron transfer salt of TCNE and Mn II (t-Bu) 4 salen exhibits weak antiferromagnetic coupling.
π SIMILAR VOLUMES
The reaction of (t-BuGaC12)r with Ar'P(H)Li (Ar' = 2,4,6-t-Bu,C6H2) affords the chloride-bridged dimer [t-BuGa(C1)P(H)Ar'I2 (1). The structure of 1 has been established by X-ray crystallography. Compound 1, C44H7RClZGa2P2, crystallizes in the monoclinic space group P2{ln wit? Z = 2, a = 10.468(1), b
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