𝔖 Bobbio Scriptorium
✦   LIBER   ✦

[MnII(t-Bu)4salen]2 and Its Reaction with TCNE

✍ Scribed by Nate Petersen; James W. Raebiger; Joel S. Miller


Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
246 KB
Volume
159
Category
Article
ISSN
0022-4596

No coin nor oath required. For personal study only.

✦ Synopsis


II (t-Bu)

4 salen has been prepared and magnetically characterized as a dimer with weak intradimer coupling of J ‫؍‬ ؊7.8 cm ؊1 (J/k B ‫؍‬ 11 K) for H ‫؍‬ ؊2JS a ' S b . The electron transfer salt of TCNE and Mn II (t-Bu) 4 salen exhibits weak antiferromagnetic coupling.


πŸ“œ SIMILAR VOLUMES


Reaction of (t-BuGaCl2)2 with Arβ€²PHLi (A
✍ Alan H. Cowley; Richard A. Jones; Miguel A. Mardones; Jerry L. Atwood; Simon G. πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 English βš– 361 KB

The reaction of (t-BuGaC12)r with Ar'P(H)Li (Ar' = 2,4,6-t-Bu,C6H2) affords the chloride-bridged dimer [t-BuGa(C1)P(H)Ar'I2 (1). The structure of 1 has been established by X-ray crystallography. Compound 1, C44H7RClZGa2P2, crystallizes in the monoclinic space group P2{ln wit? Z = 2, a = 10.468(1), b

Synthesis of 2,4-Dihydroxybenzaldehyde-I
✍ Wang Huiqin; Yang Zhibin πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 English βš– 94 KB

A new fluorescent reagent, 2,4-dihydroxybenzaldehyde-isonicotinylhydrazone (DHBI), is synthesized and characterized by elemental analysis and infrared spectra (KBr disks). The fluorescent reaction of aluminium(III) with the new reagent has been studied. The fluorescent excitation and emission wavele