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[MnIII(salen)]6[FeIII(bpmb)(CN)2]6⋅7 H2O: A Cyanide-Bridged Nanosized Molecular Wheel

✍ Scribed by Zhong-Hai Ni; Hui-Zhong Kou; Li-Fang Zhang; Chunhua Ge; Ai-Li Cui; Ru-Ji Wang; Yadong Li; Osamu Sato

Book ID
101562153
Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
170 KB
Volume
44
Category
Article
ISSN
0044-8249

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[MnIII(salen)]6[FeIII(bpmb)(CN)2]6⋅7 H2O
[MnIII(salen)]6[FeIII(bpmb)(CN)2]6⋅7 H2O: A Cyanide-Bridged Nanosized Molecular Wheel
✍ Zhong-Hai Ni; Hui-Zhong Kou; Li-Fang Zhang; Chunhua Ge; Ai-Li Cui; Ru-Ji Wang; Y 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 171 KB

Complexes 1 and 2 were synthesized by the reaction of [Mn-(salen)]ClO 4 (42.0 mg, 0.1 mmol) and K[Fe(bpmb)(CN) 2 ] [11] (48.0 mg, 0.1 mmol) or K[Fe(bpb)(CN) 2 ] [11] (46.5 mg, 0.1 mmol) in MeOH/ MeCN/H 2 O (10 mL, volume ratio 6:3:1) at room temperature. Uniform, well-shaped, red-brown single crysta