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Mn-Mediated Coupling of Alkyl Iodides and Ketimines: A Radical Addition Route to α,α-Disubstituted α-Aminoesters

✍ Scribed by Friestad, Gregory K.; Ji, An

Book ID
111678510
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
94 KB
Volume
10
Category
Article
ISSN
1523-7060

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Addition of alkyl radicals, generated fr
Addition of alkyl radicals, generated from carboxylic acids via photochemical decarboxylation, to glyoxylic oxime ether: a mild and efficient route to α-substituted α-aminoesters
✍ Yasuharu Yoshimi; Kosuke Kobayashi; Hayato Kamakura; Keisuke Nishikawa; Yoshiki 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 505 KB

Radical addition to a glyoxylic oxime ether was accomplished under mild conditions using an alkyl radical generated from a free carboxylic acid via photochemical decarboxylation. The photoreaction provided an efficient route to a-substituted a-aminoesters from carboxylic acids and oxime ether.