Vigo, Espana ˜Ä Ž Density and refractive index data in the binary mixtures xCH COOCH q 1 y 3 3 . Ž . Ž .4 Ä Ž . Ž . Ž .4 xCH CH C OH CH and xCH OH q 1 y x CH CH C OH CH , and the ternary 3 2 3 2 3 3 2 3 2 sented at T s 298.15 K over the whole range of mole fractions and atmospheric pressure. These
Mixing properties and derived magnitudes of the system {x1 CH3COOCH3+x2 CH3OH+(1−x1 −x2 )CH3(CH2)4OH} at the temperature 298.15 K
✍ Scribed by A. Rodrı́guez; J. Canosa; B. Orge; M. Iglesias; J. Tojo
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 194 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0021-9614
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✦ Synopsis
In this paper, the physical properties of densities and refractive indices have been measured and derived excess molar volumes and changes of refractive index on mixing have been calculated at T s 298.15 K and atmospheric pressure. Experimental values correspond to the Ä Ž . Ž . 4 ternary x CH COOCH q x CH OH q 1 y x y x CH CH OH and binary systems
Different polynomial functions have been fitted with the excess properties and their parameters determined. Several estimation methods are applied to compare the physical and derived properties. For the ternary systems, excess molar volumes and ternary contributions are compared with previous mixtures. A comparison is made in terms of excess molar volumes and ternary contributions to this property by variation of methylene groups of alkanol component.
📜 SIMILAR VOLUMES
## Densities and refractive indices of {x1CH3COOCH3 , and {xCH3OH + (1 -x)CH3CH(OH)CH3} have been determined experimentally as a function of the mole fraction(s) at the temperature 298.15 K and atmospheric pressure. A vibrating tube digital densimeter and an Abbe-type refractometer of synthetic s
Excess molar volumes at the temperature 298.15 K were measured for , and {xCH3(CH2)4 CH3 +(1x)CH3(CH2)3OH}. Excess molar volumes were determined using an Anton Paar DMA 60/602 densimeter. The experimental values obtained in this work were compared with results obtained using methods which estimate
Densities and refractive indices at the temperature 298.15 K of {x1CH3COCH3 + x2CH3OH + (1 -x1 -x2)CH3(CH2)4OH} and of the corresponding binary mixtures: {xCH3COCH3 + (1x)CH3(CH2)4OH}, and {xCH3OH + (1x)CH3(CH2)4OH}, have been determined experimentally as a function of the mole fraction at atmospher
Excess molar volumes V E m of the ternary mixture {x1CH3(CH2)3OH+x2CH3(CH2)4CH3 + (1-x1-x2)CH3(CH2)3NH2} at the temperatures 298.15 K and 313.15 K, and the binary mixtures {xCH3(CH2)3OH + (1-x)CH3(CH2)3NH2}, {xCH3(CH2)4CH3 + (1-x)CH3(CH2)3NH2} at T=313.15 K have been determined from density measurem