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Mixed Valent Molybdenum Monophosphates with an Interconnected Tunnel Structure A2Mo3O5(PO4)3 (A = Cs, Rb, Tl, K)

โœ Scribed by S. Ledain; A. Leclaire; M.M. Borel; J. Provost; B. Raveau

Book ID
114066937
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
416 KB
Volume
33
Category
Article
ISSN
0025-5408

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New mixed valent monophosphates \(A_{3} \mathrm{O}_{2}\left(\mathrm{MoO}_{4}\right)_{4}\left(\mathrm{PO}_{4}\right)_{4}\) with an intersecting tunnel structure have been isolated for \(A=\mathrm{Rb}, \mathrm{Tl}\). The structure of the \(\mathrm{Rb}-\) phase has been solved from a single crystal X-r

A Mixed-Valent Molybdenum Monophosphate
A Mixed-Valent Molybdenum Monophosphate with a "Butterfly"-Shaped Tunnel Structure Cs6Mo7O9(PO4)7 ยท H2O
โœ A. Guesdon; M.M. Borel; A. Leclaire; A. Grandin; B. Raveau ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 374 KB

A new mixed-valent molybdenum monophosphate \(\mathrm{Cs}_{6} \mathrm{Mo}_{7} \mathrm{O}_{9}\left(\mathrm{PO}_{4}\right)_{7} \cdot \mathrm{H}_{2} \mathrm{O}\) has been isolated by solid state chemistry. It crystallizes in the space group Pnma with \(a=10.084(1) \AA\), \(b=21.297(3) \AA\), \(c=17.491