Mixed-valence solid-solution series. Crystal structures of phosphoferrite, Fe32+(H2O)3[PO4]2, and kryzhanovskite, Fe33+(OH)3[PO4]2
β Scribed by Moore, Paul Brian.; Araki, Takaharu.
- Book ID
- 120505653
- Publisher
- American Chemical Society
- Year
- 1976
- Tongue
- English
- Weight
- 699 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0020-1669
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Two new \(\mathrm{Fe}^{\mathrm{Ill}}\) and \(\mathrm{V}^{\mathrm{ll}}\) phosphates, \(\mathrm{Ba}_{2} \mathrm{Fe}_{3} \mathrm{H}\left(\mathrm{PO}_{4}\right)_{2}\left(\mathrm{P}_{2} \mathrm{O}_{7}\right)_{2}\) and \(\mathrm{Ba}_{2} \mathrm{~V}_{3} \mathrm{H}_{2}\left(\mathrm{PO}_{4}\right)_{2}\left(\
A novel inorganic-organic framework material has been prepared hydrothermally in the iron(II)-phosphate-oxalate system. Fe4(PO4)2(C2O4)(H2O)2 crystallizes in space group P21/n, a β«Ψβ¬ 7.974(3) A s , b β«Ψβ¬ 4.817(3) A s , c β«Ψβ¬ 14.169(3) A s , β«Ψβ¬ 94.70(3)Β°, V β«Ψβ¬ 542.4(4) A s 3 , Z β«Ψβ¬ 2, final R, R β«