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Mixed-Valence and Neutral Framework Inorganic−Organic Hybrid Materials: Synthesis, Characterization, and Magnetic Properties of [{Co(N(CH) 4 N)}(V 2 O 5 ) 2 ] and [{Co(N(CH) 4 N)}V 2 O 6 ]

✍ Scribed by Khan, M. Ishaque; Yohannes, Elizabeth; Golub, Vladimir O.; O'Connor, Charles J.; Doedens, Robert J.


Book ID
127279287
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
271 KB
Volume
19
Category
Article
ISSN
0897-4756

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✍ F. Sediri; N. Etteyeb; N. Steunou; C. Guyard-Duhayon; J. Maquet; N. Gharbi; J. L 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 203 KB

A new layered vanadium oxide [H 3 N(CH 2 ) 4 NH 3 ](V 6 O 14 ) was synthesized hydrothermally under autogenous pressure at 1801C for 48 h from a mixture of H 2 N(CH 2 ) 4 NH 2 and V 2 O 5 in aqueous solution. Its structure was determined from singlecrystal X-ray diffraction at room temperature with