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Synthesis and characterization of oxorhenium(V)-catecholate complexes. Crystal and molecular structures of (CH3)4N[ReO (O2C6H4)2] and (CH3)4N[ReO(PPh3) (O2C6H4)2]·CH3OH

✍ Scribed by Peter B. Kettler; Chang Yuan-Da; Jon Zubieta; Michael J. Abrams


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
983 KB
Volume
218
Category
Article
ISSN
0020-1693

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A new layered vanadium oxide [H 3 N(CH 2 ) 4 NH 3 ](V 6 O 14 ) was synthesized hydrothermally under autogenous pressure at 1801C for 48 h from a mixture of H 2 N(CH 2 ) 4 NH 2 and V 2 O 5 in aqueous solution. Its structure was determined from singlecrystal X-ray diffraction at room temperature with