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Mixed Ruthenium–Iridium Carbonyl Cluster Complexes. Synthesis of the Anions [Ru3Ir2(CO)14]2− and [Ru3Ir2(CO)14H]− and Crystal Structures of Their [tetraphenylphosphonium]+ Salts

✍ Scribed by Alessandro Fumagalli; Maria Carlotta Malatesta; Michele Vallario; Gianfranco Ciani; Massimo Moret; Angelo Sironi


Book ID
110350826
Publisher
Springer
Year
2001
Tongue
English
Weight
172 KB
Volume
12
Category
Article
ISSN
1040-7278

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Tri- and Tetranuclear Mixed-Metal Cluste
✍ Vincent Ferrand; Georg Süss-Fink; Antonia Neels; Helen Stoeckli-Evans 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 406 KB 👁 2 views

The tetrahedral cluster anion [Ru 3 Ir(CO) 13 ] -(1) reacts with neutral hydrido clusters [HRu 2 Ir(CO) 9 (RCϵCRЈ)] (10: R = RЈ = Ph; 11: R = RЈ = Et; 12: R = Ph; RЈ = Me; 13: R = RЈ = Me). internal alkynes RCϵCRЈ to afford the alkyne derivatives [Ru 3 Ir(CO) 11 (RCCRЈ)] -(2: R = RЈ = Ph; 3: R = RЈ