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Au-Ir and Hg-Ir Mixed-Metal Carbonyl Clusters. Synthesis, Characterization, and Solid State Structure of [Ir6(CO)15(AuPPh3)2] and [Ir6(CO)14(HgCl)2]2-

✍ Scribed by Ceriotti, Alessandro; Della Pergola, Roberto; Garlaschelli, Luigi; Manassero, Mario; Masciocchi, Norberto


Book ID
127235994
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
838 KB
Volume
14
Category
Article
ISSN
0276-7333

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Tri- and Tetranuclear Mixed-Metal Cluste
✍ Vincent Ferrand; Georg Süss-Fink; Antonia Neels; Helen Stoeckli-Evans 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 406 KB 👁 2 views

The tetrahedral cluster anion [Ru 3 Ir(CO) 13 ] -(1) reacts with neutral hydrido clusters [HRu 2 Ir(CO) 9 (RCϵCRЈ)] (10: R = RЈ = Ph; 11: R = RЈ = Et; 12: R = Ph; RЈ = Me; 13: R = RЈ = Me). internal alkynes RCϵCRЈ to afford the alkyne derivatives [Ru 3 Ir(CO) 11 (RCCRЈ)] -(2: R = RЈ = Ph; 3: R = RЈ