Mixed-ligand complexes of osmium(III/IV)
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Pranab R. Basudhar; Sutapa Sinha; Pradyut K. Das; Barindra K. Ghosh
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Article
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1996
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Springer
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English
β 391 KB
A group of mixed-tris chelates of type [OsAQ2 ] [A=isonitrosoacetophenonate (A ~) and isonitrosopropiophenonate (A2); Q = deprotonated 8-quinolinol (QI) and 2-methyl-8-quinolinol (Q2)] have been prepared by two distinct synthetic approaches. [OsAQ2] +, obtained by Ce Iv oxidation of [OsAQ2], can be