Mixed Metal Base LICKOR as Key Reagent in the Synthesis of Conjugate Alkadien-1-ols. A New Route to an Insect Attractant. -Studies of the reactivity of 2-alkenyltetrahydrofurans with the LICKOR super base show that it promotes 1,4-eliminative ring fission affording conjugate alkadien-1-ols with hig
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Mixed metal base LICKOR as key reagent in the synthesis of conjugate alkadien-1-ols. A new route to an insect attractant
β Scribed by Fulvio Cominetti; Annamaria Deagostino; Cristina Prandi; Paolo Venturello
- Book ID
- 104208943
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 337 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0040-4020
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Treatment of the dimethyl acetals of citral (1) and farnesal be subjected to a Diels-Alder reaction, which allows further synthetic elaboration. In particular, in the case of farnesal (2) with the superbase "LICKOR" in THF at low temperatures induces regioselective metallation at the allylic methyl