Mixed-ligand complexes of platinum(II) and palladium(II) with 1,10-phenanthroline and aromatic chelating ligands containing OH of SH groups as photosensitizers for the generation of 1O2
✍ Scribed by S. Shukla; S.S. Kamath; T.S. Srivastava
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 848 KB
- Volume
- 47
- Category
- Article
- ISSN
- 1010-6030
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Eight complexes with the formula [M(N-N)(DHBA)] (where MS Pd(I1) or Pt(II), N-N is 2,2'-bipyridine (BPY), 2,2'-biquinoline (BIQ), l,lO-phenanthroline (PHEN), 4,7-diphenyll,lO-phenanthroline (DPP) and DHBA is 3,4\_dihydroxybenzoic acid dianion) were found to photosensitize the oxidation of 2,2,6,6-te
## Abstract A mononuclear Cu(II) complex with mixed ligands, formulated as [Cu(hypydc)(dmp)]·H~2~O (hypydc=4‐hydroxypyridine‐2,6‐dicarboxylate, dmp=2,9‐dimethyl‐1,10‐phenanthroline), was synthesized and well characterized by single crystal X‐ray diffraction analysis, as well as spectroscopic (IR, U