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Mixed Crystals Containing the Diamagnetic Complex [Mo2(SO2)(S2)(CN)8]4⊖ and the Paramagnetic Complex [Mo2(SO2)(S2)(CN)8]5⊖

✍ Scribed by Prof. Dr. Achim Müller; Dr. Werner Eltzner; Dr. Rainer Jostes; Dr. Hartmut Bögge; Dr. Ekkehard Diemann; Jürgen Schimanski; Prof. Dr. Heiko Lueken

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
255 KB
Volume
23
Category
Article
ISSN
0044-8249

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✦ Synopsis

rection) in a corresponding section of the SeF, structure are reproduced schematically at the bottom of Figure . The shortening of the c-axis in TeF, is due to the strong fluorine bridges within the polymeric structural assemblage. The fundamental similarity of the arrangements of the structural units of SeF, and TeF, in the [OlO] direction also exists in the three-dimensional crystal arrays. The possibility of a structural transformation in SeF, by a closer (pressure-induced) proximity of the axial fluorine atoms to selenium atoms of neighboring molecules cannot be ruled out.

The chemical similarity of SeF, and SFJ6] seems to be further confirmed by the-albeit up to -160°C disordered-crystal structure of SFL7', from which a formation of fluorine-bridged associates in crystalline SF4 is not to be assumed.

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