Mixed aldimine derivatives of aluminium
โ Scribed by M. Agrawal; J.P. Tandon; R.C. Mehrotra
- Book ID
- 115975666
- Publisher
- Elsevier Science
- Year
- 1979
- Weight
- 214 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0022-1902
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๐ SIMILAR VOLUMES
Synthesis of N-(Dimethylsulfamoyl)aldimines, a New Type of Aldimine Derivative. -A series of novel aldimine derivatives (III) (10 examples), important precursors in the synthesis of 4(5)-monosubstituted imidazoles, are readily prepared from aldehydes (I) and N-(dimethylsulfamoyl)amide (II) .
RhCl(COD)] 2 (2 mol%) catalyzed reactions of alkenylzirconocene chloride complexes to N-Ts, -PO(OEt) 2 and COOR aldimine derivatives were efficiently carried out in dioxane at room temperature to give allylic amine derivatives in excellent yields. This is the first example of the catalytic addition