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Mitsunobu reaction of 1,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-2-hydroxymethyl-hex-1-enitols and 1,5-anhydro-2-deoxy-4,6-O-protected-hex-1-enitols. A novel method for the synthesis of 2-C-methylene glycosides and an useful alternative to Ferrier rearrangement

✍ Scribed by Namakkal G. Ramesh; Kalpattu K. Balasubramanian


Book ID
107857430
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
932 KB
Volume
51
Category
Article
ISSN
0040-4020

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πŸ“œ SIMILAR VOLUMES


Nucleophilic addition reactions of 1,5-a
✍ Akinori Seta; Shinji Ito; Kiyohisa Tokuda; Takeshi Tamura; Yaeko Konda; Tohru Sa πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 648 KB

Reactions of the title compounds with several nucelophiles suggested that the ring oxygen atom (0-5) accelerated the reactivity of the nitro alkene moiety, but scarcely affected the stereoselectivity of the nucleophilic attack.