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Miscibility and Interactions in Blends and Complexes of Poly( N -acryloyl- N ‘-methylpiperazine) with Poly( p -vinylphenol)

✍ Scribed by Liu, Yong; Goh, S. H.; Lee, S. Y.; Huan, C. H. A.


Book ID
120346421
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
102 KB
Volume
32
Category
Article
ISSN
0024-9297

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A rare miscible polyacrylonitrile (PAN) blend system is reported. PAN is miscible with poly(pvinylphenol) (PVPh) as shown by thermal and spectroscopic studies. A single glass transition temperature was found in each blend. Infrared spectroscopic studies showed that the hydroxyl band of PVPh and the

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Poly(N-acryloyl-NЈ-methylpiperazine) (PAMP) forms complexes with four strong acidic polymers, namely, poly(styrenesulfonic acid), poly(vinylphosphonic acid), poly(acrylic acid) and poly(methacrylic acid) in ethanol/water (1:1) solution. The nature of interpolymer interactions in various complexes wa