𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Spectroscopic studies of interactions in poly(N-acryloyl-N′-methylpiperazine)/acidic polymer complexes

✍ Scribed by Y. Liu; S. H. Goh; S. Y. Lee; C. H. A. Huan

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
186 KB
Volume
38
Category
Article
ISSN
0887-6266

No coin nor oath required. For personal study only.

✦ Synopsis

Poly(N-acryloyl-NЈ-methylpiperazine) (PAMP) forms complexes with four strong acidic polymers, namely, poly(styrenesulfonic acid), poly(vinylphosphonic acid), poly(acrylic acid) and poly(methacrylic acid) in ethanol/water (1:1) solution. The nature of interpolymer interactions in various complexes was studied by Fourier transform infrared (FTIR) spectroscopy and X-ray photoelectron spectroscopy (XPS). Both the carbonyl oxygen and the amide nitrogen of PAMP are involved in hydrogen-bonding interactions. Some of the amine nitrogens of PAMP are protonated and therefore PAMP also interacts with the acidic polymers through ionic interactions.

📜 SIMILAR VOLUMES

Molecular interactions in poly(methacryl
Molecular interactions in poly(methacrylic acid)/poly(N-isopropyl acrylamide) interpenetrating polymer networks
✍ Jing Zhang; Nicholas A. Peppas 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 142 KB

## Abstract The molecular interactions between the component networks in poly(methacrylic acid)/poly(__N__‐isopropyl acrylamide) (PMAA/PNIPAAm) interpenetrating polymer networks (IPNs) were investigated using attenuated total reflectance (ATR)‐Fourier transform IR (FTIR) spectroscopy. Hydrogen‐bond

Synthesis and thermal studies of poly(N-
Synthesis and thermal studies of poly(N-acryloyl,N′-cyanoacetohydrazide) complexes with Co(II), Fe(III), and UO2(II) ions
✍ E. H. El-Mossalamy; Shaeel A. Al-Thabaiti 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 92 KB 👁 1 views

## Abstract Polymer complexes with uranium, cobalt, and iron chlorides were synthesized and investigated by elemental analysis, electronic (uv–visible), IR vibration, and magnetic moment measurements. The thermal stabilities of __N__‐acryloyl,__N__′‐cyanoacetohydrazide (ACAH) homopolymers and polym