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Miniemulsion copolymerization of vinyl acetate and butyl acrylate. III. Experimental evidence for the role of the cosurfactant

✍ Scribed by Joaquin Delgado; Mohamed S. El-Aaser; Cesar A. Silebi; John W. Vanderhoff


Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
570 KB
Volume
27
Category
Article
ISSN
0887-624X

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πŸ“œ SIMILAR VOLUMES


Miniemulsion copolymerization of vinyl a
✍ Joaquin Delgado; Mohamed S. El-Aasser; Cesar A. Silebi; J. W. Vanderhoff πŸ“‚ Article πŸ“… 1990 πŸ› John Wiley and Sons 🌐 English βš– 1018 KB

## Abstract The copolymerization kinetics of conventional emulsions and miniemulsions of 50:50 and 25:75 molar ratios vinyl acetate–butyl acrylate monomer mixtures were studied using sodium hexadecyl sulfate as surfactant. Hexadecane was the cosurfactant used in the preparation of the miniemulsions

Reactivity ratios and monomer partitioni
✍ VΓ­ctor M. Ovando-Medina; Hugo MartΓ­nez-GutiΓ©rrez; Eduardo MendizΓ‘bal; Miguel A. πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 149 KB πŸ‘ 3 views

## Abstract The true monomer reactivity ratios for the vinyl acetate/butyl acrylate system were determined with experimental data from the cumulative copolymer composition at low, intermediate, and high conversions and with the monomer partitioning among the aqueous, microemulsion droplet, and poly

Free radical copolymerization behavior o
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No alternating copolymers of vinyl acetate (VAc) and butyl acrylate (BA) were obtained by free radical copolymerization in the presence of GeCl 4 and (compared with the acrylic acidÈvinyl acetate copolymerization BCl 3 system). By ultraviolet spectral analysis, it was concluded that both and BCl 3 c