## Abstract The copolymerization kinetics of conventional emulsions and miniemulsions of 50:50 and 25:75 molar ratios vinyl acetateβbutyl acrylate monomer mixtures were studied using sodium hexadecyl sulfate as surfactant. Hexadecane was the cosurfactant used in the preparation of the miniemulsions
Miniemulsion copolymerization of vinyl acetate and butyl acrylate. III. Experimental evidence for the role of the cosurfactant
β Scribed by Joaquin Delgado; Mohamed S. El-Aaser; Cesar A. Silebi; John W. Vanderhoff
- Publisher
- John Wiley and Sons
- Year
- 1989
- Tongue
- English
- Weight
- 570 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0887-624X
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## Abstract The true monomer reactivity ratios for the vinyl acetate/butyl acrylate system were determined with experimental data from the cumulative copolymer composition at low, intermediate, and high conversions and with the monomer partitioning among the aqueous, microemulsion droplet, and poly
No alternating copolymers of vinyl acetate (VAc) and butyl acrylate (BA) were obtained by free radical copolymerization in the presence of GeCl 4 and (compared with the acrylic acidΓvinyl acetate copolymerization BCl 3 system). By ultraviolet spectral analysis, it was concluded that both and BCl 3 c